The biggest concern I'd have is based upon your genset engine is sized to efficiently drive the generator and when the generator is under full load the engine is also running at full load. After looking at efficiencies on alternators (friction and heat losses) you would be looking at more energy requirement to drive the additional alternator at 100 amps than to add a 20 amp 120VAC load on the existing generator. So as your genset is already running at close to maximum duty cycle as you say, I can't see where adding a less efficient form of electrical generation on the engine gains anything at all. What am I missing?